Unlike Mareep, Flaaffy's evolution should not be delayed, as Ampharos learns ThunderPunch naturally at level 30, right after evolving if it cannot evolve at that level for some reason, the move can still be learned, but only through the Goldenrod Dept. The evolution may optionally be postponed until level 16 to have Flaaffy learn Thunder Wave early Flaaffy gets it too, but only two levels later.
Mareep's initial moveset, when caught at the earliest possible location, consists of Tackle and Growl.
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Feel free to anticipate or postpone any battles as needed. From this point onwards, you can fight the gyms in any order, though you will need to retrieve the Machine Parts from the Cerulean City gym before you have access to the earlier portion of Kanto.
There is much that Ampharos has to offer in this game, and in many other games as well. It is by far the most common of all, it can be accessed from a very early point in the game, and it evolves quickly, as well as having excellent stats - almost beastly for the setting it is found in. This line is exclusive to Gold and Silver, and cannot be found in Crystal. Mareep can be found on Routes 32, 42 and Flaaffy can also be found on Routes 42 and It is most common on Route 42, and generally tends to be more common during the daytime rather than at dawn or night.